Bio-based polyamides and foams
The project focused on developing a new, completely bio-based high-performance polyamide called Caramid. The material has a significantly higher glass transition temperature than the conventional polyamides PA6 and PA6.6. This makes it more stable and allows for completely new applications. Both the synthesis and processing methods of the bio-based polyamide have been improved to such an extent that it offers a competitive alternative to petroleum-based polyamides, for example for use as an environmentally friendly tire cord in the automotive industry.
A decisive milestone was reached in 2024 with the successful synthesis and purification of almost 20 kilograms of the precursor as well as its polymerization to Caramid. At the same time, strategies were developed to produce customized types of Caramid for fiber and foam applications. Samples of the spun fibers and foams showed promising results in terms of processability and mechanical properties, even at this early stage.
Biohybrid, functional polymers
A second focus was on the functionalization of technical polymers such as polyethylene terephthalate (PET) and cellulose. Bioactive additives were used to achieve, for example, hydrophilic surfaces, bio-based flame retardancy, and enzymatically controlled degradation. Stabilized enzymes, which will enable efficient degradation of PET under mild conditions, were successfully integrated. Prototypes of diagnostic devices as well as completely biobased hydrophobic cellulose were also produced.
Digitalization and sustainability
The first virtual material models for protective textiles and technical components such as tires were created and validated. The integration of simulation, material analysis, and ecological assessment enables the rapid, targeted development of sustainable materials, right through to virtual demonstrators.
Outlook
Emphasis in the coming project year will be on scaling up the processes and applications. One focus will be on producing demonstrators for protective clothing and technical foams. The results from SUBI²MA show how bio-based and biohybrid materials can be brought to industrial maturity through intelligent process control and interdisciplinary collaboration.